XMPP is an open-standard communications protocol. It can be used for instant messaging, but also for various other tasks. XMPP is a acronym for "Extensible Messaging and Presence Protocol". GTalk uses XMPP with a few extensions, but it remains standard compliant.

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Is there any version of gtalk supporting multiple accounts which works with 2.3/cm7

Gtalk 1.3 doesn't support multiple accounts: it just connects with the main one, with no apparent way to switch it. Upgrading to hangouts technically works, but it doesn't even bother to display user ...