I have two Twitter accounts in my Twitter app, one personal and one for work. I added the personal one first, and it appears first in the Android Accounts settings. I want the Twitter app to use the personal account when it first opens, but it always defaults to the other one - can I change this?
I would suggest logging out of both and signing into your personal account first. Then the work account. This should then default to the first account you signed up with...
I can't comment as I don't have enough rep yet.