If 3G/UMTS is available for calls depends on the country you are living in. A lot of countries have shut down older mobile networks like GSM/2G and 3G or planning to do so.
But every mobile operator and every country it can be different what networks are shut down.
- In Germany the 2G network stays, only 3G is shut down.
- In Switzerland Swisscom has switched of 2G completely, 3G is still active
- In USA 2G networks are mostly shut down already and 3G networks are mostly shut down next year source.
- In some Asian countries as far as I remember 2G and 3G has been shut down
So the answer is no, 3G and 4G are totally independent form each other.
Therefore today buying a phone that has no 4G + VoLTE support is not a good idea.