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This is the question I had the most fun answering so far. It's a simple but really effective regex technique that can be used in a surprisingly large number of situations.
Options for Forced Failure (ignore the accepted answer). This is just for fun—the standard is (?!) or (*F) in Perl and PCRE.
Work in progress—I really want to add more here. By far the greatest thrill I get on Stack is when I read an answer that makes me go "Aha!..." and grasp a way of doing things that is so much more efficient than anything I had come up with. I've been blown away quite a few times. And one thing that's for sure is there's no shortage here of people who are a lot brighter than me. :)